Thursday night marks an all-new episode of USA's "White Collar" in which "Peter and Neal seek to uncover a smuggling ring in Little Odessa by infiltrating the criminal underworld," the official synopsis reads.

One preview of season 5, episode 6, titled "Ice Breaker," suggests that the climax unravels along with a new developing case. Also in the episode, rare book expert and Neal's potential love-interest, Rebecca Lowe, makes a return. Neal and Mozzie ask her about the rare book and the page that Neal had managed to steal for Curtis Hagen, however, it looks like that Neal may be able to figure out what the secret page is hiding on his own.

Also in the clip, Mozzie is seen telling Neal, "You can slip away and the big brother will be none the wise."

After Neal finally gets the tracking anklet off of his ankle to infiltrate the underworld, Peter realizes that Neal went off and wants to find out where he went exactly.

In another sneak peak exclusively obtained by E!, Neal gets Mozzie and June to disguise themselves as member of the Art Crimes Division.

USA's "White Collar" is a police procedural drama that captures the nail-biting saga of Tim DeKay and Neal Caffrey. Caffrey is a white collar criminal who agrees to help the FBI catch other white collar crooks using his expertise as an art and securities thief, counterfeiter and racketeer.

Season 5, episode 6 of "White Collar" will air Thursday, November 21 on USA at 9 p.m. Watch the previews below.